Alumina-Zirconia Composite

Alumina-Zirconia Composite (ZTA/ATZ)

Alumina-zirconia (ATZ) ceramic combines the unique properties of alumina (Al₂O₃) and zirconia (ZrO₂) to create a versatile and resistant material, often used in demanding industrial applications. Zirconia reinforces the toughness and fracture resistance of alumina, a naturally hard and abrasion-resistant material. This blend compensates for the typical brittleness of ceramics, while maintaining excellent hardness, good thermal stability, and high chemical resistance.

ZTA (zirconia-toughened alumina) and ATZ (alumina-toughened zirconia) ceramics differ in their composition, one containing a majority of alumina, the other a majority of zirconia. These two configurations allow the properties to be adapted as required: ZTA for better hardness and chemical resistance, and ATZ for higher toughness. However, these composites are still expensive to produce and require precise control of the sintering processes to guarantee a homogeneous microstructure. They can also be sensitive to thermal shock, depending on the proportions of alumina and zirconia used.

Alumina-zirconia ceramics have a wide range of applications in sectors such as the biomedical industry for implants (hip prostheses), aeronautics for engine parts and thermal coatings, and industrial tooling where wear resistance is essential. This composite material offers an excellent compromise between hardness, strength and toughness, making it indispensable in extreme environments and high value-added applications.

Composition

Component ZTA (Zircone-Toughened Alumina) ATZ (Alumina-Toughened Zirconia) Comment
Al2O3 (alumina) 70 - 90 % 10 - 30 % Provides hardness and wear resistance; main phase in ZTA
ZrO2 (zirconia) 10 - 30 % 70 - 90 % Improves tenacity, increases resistance to impact; main phase in ATZ
Y2O3 (yttrium oxide) 2 - 5 % 2 - 5 % Stabilizes the zirconia to prevent its phase transformation
SiO2 (silicon oxide) < 0,05 % < 0,05 % Common impurity, sometimes added to increase hardness
Fe2O3 (iron oxide) < 0,01 % < 0,01 % Present in traces, can alter color and hardness
MgO (magnesium oxide) < 0,01 % < 0,01 % Improves thermal stability
The alumina or zirconia content mainly determines the mechanical properties: a higher alumina content (ZTA) improves hardness and chemical resistance, while a higher zirconia content (ATZ) increases toughness and impact resistance. Yttrium oxide is often added to stabilize zirconia, thus preventing degradation under thermal and mechanical stress.

Typical properties

Flexural strength
500 - 1200 MPa
Elasticity modulus
200 - 300 GPa
Density
4,2 - 5,8 g/cm3
Hardness
12 - 14 GPa

Typical properties; should not be interpreted as specifications.
EN ISO 6507, ASTM D790.

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